Vivien Leigh and Laurence Olivier
Vivien Leigh and Laurence Olivier have been each nominated for Oscars in 1940 on the twelfth Academy Awards. She was up for Finest Actress, and received, for Gone with the Wind. He was nominated for Finest Actor for Wuthering Heights. They have been married in 1940 and divorced in 1960.
Rachel Roberts and Rex Harrison
Rachel Roberts and Rex Harrison have been each nominated for Oscars in 1964 on the thirty sixth Academy Awards. She was nominated for Finest Actress for This Sporting Life and he was nominated for Finest Actor for Cleopatra. They have been married in 1962 and divorced in 1971.